What version are you using? Have you synced TO aws successfully, yet?
Whats the error exactly? Can you copy/paste the error line(s)?
Whats the command line you are using? It should be something along the lines of
s3sync.rb -v -r -s BUCKET:SOURCE TARGET
assuming your variables are all set (which you have, otherwise it wouldn't start) and you are using ssl-encrypted traffic (-s).